Ingestion: Abdominal cramps. Effects of exposure to Lithium: Fire: Flammable. MDL number MFCD00011078. Fires may be fought but only from safe fire fighting distance, evacuate all persons from immediate area of fire. T n��ë��>T�u#����NF���0�L����ɷ�����&��0$�ޓ�������J���M]�y������t8xu8]����"rѮ+eմ��F��S�[}|k6�m�ټ������n�2�w:��'���� ���~�Z���W�&������6�����^���NA嘃`f=.�T�j�6� *�X��`=� Section 3: Hazards Identification. 1962, Chem. Lithium chloride is used as a relative humidity standard in the calibration of hygrometers. Explosion: Risk of fire and explosion on contact with combustible substances and water. Lithium chloride is a chemical compound with the formula LiCl. PubChem Substance ID 24852187. 1960]. [11], Lithium chloride has been shown to have strong acaricidal properties, being effective against Varroa destructor in populations of honey bees. �%��U��M�y�!K�^��5�¼�AOe��Süupk�w�Ƽ{"�Y��w�߷�浫���S/����J eψa������5���s_��؟nڂK��YG�@�1���(c���)�%�r�7�ޤ����'��lJC��X 5�? Shortness of breath. 5.2 Special hazards arising from the substance or mixture Hydrogen chloride gas, Lithium oxides Hydrogen chloride gas, Lithium oxides 5.3 Advice for firefighters Wear self-contained breathing apparatus for firefighting if necessary. LiCl is also used as a brazing flux for aluminium in automobile parts. Potential Health Effect Eye: Causes moderate eye irritation. Many reactions may cause fire or explosion. (lithium, sulfuryl chloride, thionyl chloride, chlorine) are considered hazardous under US OSHA and are subject to the requirements of 29 CFR 1200 Hazard Communication. 3 Effective date : 10.24.2014 Page 2 of 7 Lithium Chloride, Reagent Created by Global Safety Management, Inc. -Tel: 1-813-435-5161 - www.gsmsds.com This deliquescent salt forms a self-solution when exposed to air. Laboured breathing. Jr,XH�Q��ƻ/�W�JJ���]�p��="�'�����!�jl��x��tI�G����.�E����EN�>�+J�;P�YF�T��|$��{()F%����{E���[ Y �f{BC�@تݯ5��jG׽�i��="�! %PDF-1.6 %���� The electrolyte is mainly solution of Lithium chloride (LiCl), and aluminum chloride (AlCl 3) in Thionyl chloride (SOCl 2). Also, in biochemical applications, it can be used to precipitate RNA from cellular extracts.[8]. ;(Q�c+�Z�JY��V���'"�7�XJ˵��p���d~��Mt�R~���ˈY�Z>���&o�ә�9j8|��k8|��إ�s.�lw��;��h}4ҳ�Y���L`��1��ʧ��gm�_6��g����٢C�l=���8yv� ���d��%��S?�+�#�,�3�2���=JLi��w! 7447-41-8 Lithium chloride min 99% 231-212-3 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW Harmful in contact with skin and if swallowed. D ECO #11598 P a g e 1 Material Safety Data Sheet Product Name: LITHIUM THIONYL CHLORIDE CELLS AND BATTERIES Hermetically-Sealed Lithium Thionyl Chloride Cells & Batteries All Electrochem 100, 150, 150/165MR, 180/180MR, 200/200MR series, QTC, MWD, VHT Cells and Batteries H�̗Mk�@�����jG�o9d������B���/�@Ӕ���^���M֘���k�<3�����,N��������ԕ���F�ÇWu%����G1z�����Hp]W�����`�1uW.t�1M�i�[�� c��14��1]��ki;K�A~��Ur��L��vZ�s�=�P>�m :�YWA���at. Lithium Chloride No exposure limit established No exposure limit established Appropriate Engineering Controls : Whenever possible the use of local exhaust ventilation or other engineering controls is the preferred method of controlling exposure to airborne dust … Treatment with Pamelor could be resumed 24 hours after the last dose of linezolid or intravenous methylene blue (see WARNINGS). It is used as a dessicant. 5.4 Further information No data available. It is used as a desiccant for drying air streams. N… Gives off irritating or toxic fumes (or gases) in a fire. Skin: Redness. Lithium chloride CAS 7447-41-8 for analysis EMSURE® ACS,Reag. Lithium chloride lbs lbs lbs SARA Hazard Categories: Acute Chronic Flammability Pressure Reactivity Lithium chloride Clean Air Act Categories: SOCMI HAP Volatile HAP Organic HAP Ozone Depleting Lithium chloride The information presented above is offered for informational purposes only. Irritating to eyes and skin. Lithium chloride is a stable compound incompatible with strong oxidizing agents, strong acids, bromine trichloride, bromine trifluoride. Info. Pain. Molecular Weight 42.39 . Severe deep burns. Dehydration, weight loss, slurred speech, blurred vision, sensory loss, ataxia (failure of muscular coordination), tremors, and convulsions may occur. Linear Formula LiCl . Material Safety Data Sheet Lithium chloride MSDS Section 1: Chemical Product and Company Identification Product Name: Lithium chloride Catalog Codes: SLL1366 CAS#: 7447-41-8 RTECS: OJ5950000 TSCA: TSCA 8(b) inventory: Lithium chloride CI#: Not available. Large doses of lithium may cause dizziness, prostration, and kidney damage. [5] In more specialized applications, lithium chloride finds some use in organic synthesis, e.g., as an additive in the Stille reaction. May … Product Name: Lithium chloride. Lithium chloride has been extensively tested for REACH registration Acute Effects From Overexposure: No data available for the formulation. Section 1: Chemical Product and Company Identification. LITHIUM CHLORIDE . Pain. ��c��}��M�(�Ohv�-ʿ (�s� endstream endobj 406 0 obj <>stream Lithium chloride 7447-41-8X -231-212-3X X XXKE-22552 U.S. Federal Regulations SARA 313 Not applicable SARA 311/312 Hazard CategoriesSee section 2 for more information CWA (Clean Water Act) Not applicable Clean Air Act Not applicable OSHA - Occupational Safety and Health Administration Not applicable CERCLA Not applicable 402 0 obj <> endobj 424 0 obj <>/Filter/FlateDecode/ID[<75F8B29C5E5C094E8E8A203404A1AD96>]/Index[402 66]/Info 401 0 R/Length 109/Prev 456671/Root 403 0 R/Size 468/Type/XRef/W[1 3 1]>>stream Skin burns. Symptoms may be delayed. 6bd�H�@1�:� Cc7�����s�L�s�4���{�iWzm�} )���� �y�. While the citrate, carbonate, and orotate salts are currently used to treat bipolar disorder, other lithium salts including the chloride were used in the past. CAS#: 7447-41-8. Safety Data Sheet according to 29CFR1910/1200 and GHS Rev. [6] Mono-, tri-, and pentahydrates are known. [13][14][15], Except where otherwise noted, data are given for materials in their, ChemIDplus - 7447-41-8 - KWGKDLIKAYFUFQ-UHFFFAOYSA-M - Lithium chloride - Similar structures search, synonyms, formulas, resource links, and other chemical information, Ullmann's Encyclopedia of Industrial Chemistry, "Large-scale preparation of graphene by high temperature insertion of hydrogen into graphite", "Lithium chloride effectively kills the honey bee parasite, https://en.wikipedia.org/w/index.php?title=Lithium_chloride&oldid=996316359, Chemical articles with multiple compound IDs, Multiple chemicals in an infobox that need indexing, Pages using collapsible list with both background and text-align in titlestyle, Articles containing unverified chemical infoboxes, Creative Commons Attribution-ShareAlike License, R. Vatassery, titration analysis of LiCl, sat'd in Ethanol by AgNO, This page was last edited on 25 December 2020, at 21:15. eCl@ss 38050203 . Cough. Fires may be fought but only from safe fire fighting distance, evacuate all persons from immediate area of fire. May cause headache, muscle weakness and incoordination, and confusion. It is not toxic by ingestion, but by its corrosive nature can be irritating to the skin and eyes, it can also irritate the nostrils (National Institute for Occupational Safety and Health, 2015). Additionally, lithium chloride can itself be used as a hygrometer. (lithium, thionyl chloride) are considered hazardous under US OSHA and are subject to the requirements of 29 CFR 1200 Hazard Communication.. Lithium Battery Safety With proper use and handling, lithium batteries have demonstrated an excellent safety record. SUPPLEMENTARY SAFETY AND HEALTH DATA: If the battery is broken or leaked the main hazard is the electrolyte. NACRES NA.23 No envisaged effects other than acute effects from local irritation [�� ����x����2L��?���j7�Ea�Px���Y�sE�GՖ6�`9b��������+��$x�i�+�{��W*n˕����b��u�R��eXKV�m��@ �S��{�U The electrolyte is mainly solution of Lithium chloride (LiCl), and aluminum chloride (AlCl 3) in Thionyl chloride (SOCl 2). Lithium chloride, anhydrous Revision Date 18-Jan-2018 Autoignition Temperature Explosion Limits Upper No data available Lower No data available Sensitivity to Mechanical ImpactNo information available Sensitivity to Static DischargeNo information available Specific Hazards Arising … Duration of exposure, concentration of the substance >V��DUg_?�ٴ�ӯu����Uq�Y ���-�:���X���%�u8�{Y}�����������s��ގ�vfY��o ���MB͊���Z� �uH�Ь�J?�/���mP8��1���4gR:͙�L��(Mj���P�s�lO��h5�枠8:=>���N��&%��+��|������Zxku|��M>FH,c`�X�`��. Chronic toxicity symptoms following ingestion of nonlethal doses of lithium chloride with … 1:380. Lithium (Li) OSHA PEL N/A ACGIH TLV Not established Thionyl Chloride Aluminum Chloride (AlCl3) 1.0 ppm (4.9 3mg/m ) 2 3mg/m 1.0 ppm (4.9 3mg/m ) 2 mg/m3 Lithium Chloride Not established Not established SECTION 3 - Hazards Identification **DANGER** INTERNAL CONTENTS ARE EXTREMELY HAZARDOUS. Eyes: Redness. Maleic anhydride decomposes explosively in the presence of lithium [Chemical Safety Data Sheet SD-88. If a battery ruptures, may be … [5] Anhydrous LiCl is prepared from the hydrate by heating with a stream of hydrogen chloride. The salt is a typical ionic compound (with certain covalent characters) , although the small size of the Li ion gives rise to properties not seen for other alkali metal chlorides, such as extraordinary solubility in polar solvents (83.05 g/100 mL of water at 20 °C) and its hygroscopic properties. Material Safety Data Sheet or SDS for Lithium chloride 105679 from Merck for download or viewing in the browser. Lithium Coupon. Lithium Chloride is an antiviral metal halide utilized in a variety of assays to study cell-fate and neurobiology. Lithium chloride powder, ≥99.98% trace metals basis CAS Number 7447-41-8. ��Ʉ��[H8���s\�����`���E$Y�}u1��_ The equilibrium LiCl concentration in the resulting solution is directly related to the relative humidity of the air. LEAKING FLUID IS CORROSIVE. safety hazards of Copper Chloride to potentially exposed workers. F3��-�5�"���:܂���.u�N�m� '0R l�;� �ü�,���8�8�:��H�} In case of contact with eyes, check for wearing contact lenses and remove them immediately. [12], Lithium salts affect the central nervous system in a variety of ways. 6: … Material Safety Data Sheet Lithium chloride MSDS Section 1: Chemical Product and Company Identification Product Name: Lithium chloride Catalog Codes: SLL1366 CAS#: 7447-41-8 RTECS: OJ5950000 TSCA: TSCA 8(b) inventory: Lithium chloride CI#: Not available. 1956]. 1. Causes redness and pain. In developing Xenopus embryos, lithium chloride is observed to exert inhibition of GSK-3β (glycogen synthase kinase-3β), yet not reported to be a general inhibitor of other protein kinases. MSDS-0002 Rev. Burning sensation. }�,@����)�����H �` E0� endstream endobj 403 0 obj <>/Metadata 16 0 R/Pages 400 0 R/StructTreeRoot 22 0 R/Type/Catalog>> endobj 404 0 obj <>/MediaBox[0 0 630 810]/Parent 400 0 R/Resources<>/ProcSet[/PDF/Text/ImageB/ImageC/ImageI]/XObject<>>>/Rotate 0/StructParents 0/Tabs/S/Type/Page>> endobj 405 0 obj <>stream h��X�n7�}Iи���|�IZ�n]���om�dHJ�}�pW�ʖ��b䡅�"��f�̜��$��� m�De^y�Qx�5R()�a�P�T�P6B��H:T�P��`�ˡB/�,2Ahmx�(���R�@؂U�H^�ja��a��+Y�� 5.4 Further information No data available SECTION 6: Accidental release measures 6.1 Personal precautions, protective equipment and emergency procedures �('��X˘��P���� �C�T�� ��8w+���xq|.�2��"��#c�(HZ���G�S�|��N*�;� One instance of reversible noticeable hepatotoxicity has been reported. 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